Surface and Interface Control on Photochemically Initiated Immobilization
نویسندگان
چکیده
منابع مشابه
Immobilization of Xanthate Agent on Titanium Dioxide and Surface Initiated RAFT Polymerization.
Surface modification of titanium dioxide (TiO2) nanoparticle is essential to control its surface properties, thereby to enhance its cell penetration capability, reduce its cytotoxicity, or improve its biocompatibility. In order to graft polyvinyl acetate onto TiO2 nanoparticles, xanthate was chemically immobilized on the surface of TiO2 by acylation followed by nucleophilic substitution with a ...
متن کاملInfluences of Surface Characteristics and Modified Asphalt Binders on Interface Shear Strength
Weak bonding between layers of pavement leads to damages on the composite pavement. Bonding plays an important role in the durability and maintenance of composite pavement layers. The present study evaluates the factors effective in bond strength of the interface between concrete and asphalt pavements. The factors considered for this purpose include steel slag percentage in the concrete pavemen...
متن کاملPressure dependent product formation in the photochemically initiated allyl + allyl reaction.
Photochemically driven reactions involving unsaturated radicals produce a thick global layer of organic haze on Titan, Saturn's largest moon. The allyl radical self-reaction is an example for this type of chemistry and was examined at room temperature from an experimental and kinetic modelling perspective. The experiments were performed in a static reactor with a volume of 5 L under wall free c...
متن کاملControl of surface properties using fluorinated polymer brushes produced by surface-initiated controlled radical polymerization.
Surface-grafted styrene-based homopolymer and diblock copolymer brushes bearing semifluorinated alkyl side groups were synthesized by nitroxide-mediated controlled radical polymerization on planar silicon oxide surfaces. The polymer brushes were characterized by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS), and time-dependent water contact angle mea...
متن کاملA photochemically initiated chemistry for coupling underivatized carbohydrates to gold nanoparticles.
The sensitive optoelectronic properties of metal nanoparticles make nanoparticle-based materials a powerful tool to study fundamental biorecognition processes. Here we present a new and versatile method for coupling underivatized carbohydrates to gold nanoparticles (Au NPs) via the photochemically induced reaction of perfluorophenylazide (PFPA). A one-pot procedure was developed where Au NPs we...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2006
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja062802l